I bought the season on Ps3, then i gave the console to my brother.
Is it possible to play it on my PC as well, or would I have to buy another version?
You'll have to purchase a second copy to play on PC -- the PS3 purchase was processed by Sony, and Telltale has no record of that sale.
In general, there's only one cross-platform option: you can get both PC and Mac versions in one purchase if you buy directly from Telltale or from Steam.
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In general, there's only one cross-platform option: you can get both PC and Mac versions in one purchase if you buy directly from Telltale or from Steam.